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TN型废液晶热解产物研究
引用本文:梁继军,郭玉文,刘景洋,乔琦,张建强,王新杰. TN型废液晶热解产物研究[J]. 燃料化学学报, 2010, 38(3): 380-384
作者姓名:梁继军  郭玉文  刘景洋  乔琦  张建强  王新杰
作者单位:1.School of Environmental Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China; ,2.Chinese Research Academy of Environmental Sciences, Beijing 100012, China
基金项目:环保部公益项目,中国环境科学研究院科研业务专项 
摘    要:氮气气氛下,以TN型液晶为实验材料,利用TGA-FTIR联用仪研究热解失重特征及过程产物;同时利用GC-MS对管式炉实验系统热解产物进行分析。结果表明,TN型液晶热解失重起始温度为120℃,剧烈失重温度为220℃~430℃;热解产物除了含CO2外,还含有1~5个碳原子官能团的苯、苯酚、苯呋喃等组成的芳香族化合物、多环芳烃以及丙烷为主的烃类有机物。这些有机物绝大多数是有毒有害物质,可进一步通过焚烧热解产物来实现TN型废液晶无害化处理。

关 键 词:电子废弃物  热解  TN型液晶  液晶显示器  
收稿时间:2009-11-03

Studies on the pyrolysis proudcts of waste TN-liquid crystal
LIANG Ji-jun,GUO Yu-wen,LIU Jing-yang,QIAO Qi,ZHANG Jian-qian,Wang Xin-jie. Studies on the pyrolysis proudcts of waste TN-liquid crystal[J]. Journal of Fuel Chemistry and Technology, 2010, 38(3): 380-384
Authors:LIANG Ji-jun  GUO Yu-wen  LIU Jing-yang  QIAO Qi  ZHANG Jian-qian  Wang Xin-jie
Abstract:The pyrolysis weight loss of twisted nematic liquid crystal was studied in nitrogen atmosphere by TGA FTIR. The pyrolysis products from tube furnace experimental system were analyzed GC-MS. The result indicates that the temperature of initial weight loss is 120℃ and that of apparent weight loss is 220℃~430℃. The pyrolysis products are mainly aromatic compounds besides carbon dioxide, which include benzene, phenol, benzene furan with 1~5 carbon functional groups, polycyclic aromatic hydrocarbons and hydrocarbon organic matters mainly composed of propane. Most of the organic matters are poisonous and harmful and can be harmless by further incinerating.
Keywords:WEEE  pyrolysis  twisted nematic liquid crystal  liquid crystal displayer  
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