3-羟基-1-金刚烷甲酸钴邻菲略啉配合物的合成和晶体结构

以硫酸钻、邻菲咯啉（phen）和3-羟基-1-金刚烷甲酸（HOC10H14COOH）为原料，合成了配合物Co（HOG10H14COO）2（H2O）（phen）]·H2O；利用元素分析、红外光谱、热重分析对产物进行了表征，采用单晶X射线衍射方法测定了其晶体结构．结果表明，所合成的配合物C34H42N2O8Co属于单斜晶系，空间群C2／c，a=2．69798（7）nm，b=1．14319（3）nm，c=2．29092（6）nm，β=120．498（1）°，V665．63，F（000）=2808，Dc=1．452g·cm^-3，μ（Mo-Kα）=0．765mm^-1;R1=0.0805,wR2=0.2209,其通过氢键和π-π堆积作用相结合，形成稳定的二维超分子结构．

Synthesis and Crystal Structure of Cobalt Complex with 3-Hydroxy-1-adamantanecarboxylic Acid

A novel cobalt complex, Co（HOG10H14COO）2（H2O）（phen）]·H2O was synthe sized from COSO4 · 7H2 O, phen and 3-hydroxy-l-adamantanecarboxylic acid （HOC10H14 COOH）. It was characterized by means of elemental analysis, infrared spectrometry, and ther- mogravimetric analysis. At the same time, its crystal structure was determined by making use of single crystal X-ray diffraction technique. Results show that the synthetic complex, C34 H42 N2 O8Co, crystallizes in the monoclinic system and belongs to space group C2/c,a=2.69798（7）nm,b=1.14319（3）nm,c=2.29092（6）nm,β=120.498（1）°,V665.63,F（000）=2808,Dc=1.452g·cm^-3,μ（Mo-Kα）=0.765mm^-1;R1=0.0805,wR2=0.2209, It exists in stable two dimensional supermolecular structure through hydrogen bonds and π-π interaction.