Interaction of styrene with triphenylphosphinecobalt complexes |
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Authors: | F K Shmidt V V Sarayev L O Nindakova V A Gruznykh S M Krasnopolskaya and Y S Levkovskii |
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Institution: | (1) Zhdanov State University, Irkutsk, USSR |
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Abstract: | The interaction of the cobalt phosphine complexes Co(N2)(PPh3)3, HCo(N2)(PPh3)3 and H3Co(PPh3)3 with styrene yields mono and dinuclear complexes identified by the ESR method. A paramagnetic complex, Co(PPh3) (styrene)2, is one of the intermediates in the catalytic hydrogenation of styrene.
Co(N2)(PPh3)3, HCo(N2)(PPh3)3 H3Co(PPh3)3 . , Co(PPh3) ()2. |
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