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A Facile Route to Group 13 Difluorodiorganometalates:
Authors:Roesky   Stasch   Hatop   Rennekamp   H Hamilton D   Noltemeyer   Schmidt
Affiliation:Institut für Anorganische Chemie der Universit?t Tammannstrasse 4, 37077 G?ttingen (Germany).
Abstract:
A facile synthesis utilizing tetra-n-butylammonium hydrogen difluoride and Group 13 alkyl compounds leads to the soluble salts 1 - 4. Compound 1 is the smallest difluoro-diorganoaluminate so far characterized. The corresponding gallium and indium derivatives 3 and 4 are not sensitive to moisture.
Keywords:
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