| (S2W(μ-S)2OW(μ-S)2WS2]2-的合成和性质研究 |
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| 引用本文： | 金国新,忻新泉,陈汉文,戴安邦. (S2W(μ-S)2OW(μ-S)2WS2]2-的合成和性质研究[J]. 无机化学学报, 1986, 2(4): 95-97 |
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| 作者姓名： | 金国新 忻新泉 陈汉文 戴安邦 |
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| 作者单位： | 南京大学配位化学研究所(金国新，忻新泉，陈汉文)，南京大学配位化学研究所(戴安邦) |
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| 摘 要： | 本文提出在酸性水溶液中,合成钨硫原子簇状化合物[(n-Bu)_4N]_2[S_2W(μ-S)_2OW(μ-S)_2WS_2]和的新方法,并进行了化学分析和红外光谱、电子光谱的测定。
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| 关 键 词： | 钨 硫 W-S簇状化合物 四硫代钨酸铵 |
| 收稿时间： | 1986-07-06 |
SYNTHESIS OF [S_2W(u-S)_2OW(u-S)_2WS_2]~(2-) AND STUDY ON ITS PROPERTIES |
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| Jing Guoxin,Xin Xinquan,Chen Hanwen and Dai Anbang. SYNTHESIS OF [S_2W(u-S)_2OW(u-S)_2WS_2]~(2-) AND STUDY ON ITS PROPERTIES[J]. Chinese Journal of Inorganic Chemistry, 1986, 2(4): 95-97 |
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| Authors: | Jing Guoxin Xin Xinquan Chen Hanwen Dai Anbang |
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| Abstract: | [(n-Bu)4N]2CS2W(u-S)2OW(u-S)2WS2] (I) and [ N-C18H34]2[S2W(u-S)2OW(u-S)2WS2H (II) have been prepared by acidification of tetrathio-tungstate (WS/~) in aqueous solution. The compounds were characterized by elemental analyses, infrared spectra and electronic spectra. |
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| Keywords: | tungsten sulfur W-S cluster ammonium tetrathiotungstate |
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