Formation of the intermediate-spin iron(III) porphyrin complexes with (dxz, dyz)3(dxy)1(dz2)1 electron configuration |
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| Authors: | Sakai Takanori Ohgo Yoshiki Ikeue Takahisa Takahashi Masashi Takeda Masuo Nakamura Mikio |
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| Institution: | Department of Chemistry, School of Medicine, Toho University, Ota-ku, Tokyo 143-8540, Japan. |
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| Abstract: | On the basis of the difference in meso-13C chemical shifts, we have concluded that the intermediate-spin iron(III) complexes with highly ruffled and highly saddled porphyrins have different electron configurations. While the latter has a conventional (dxy)2(dxz, dyz)2(dz2)1, the former adopts a novel (dxz, dyz)3(dxy)1(dz2)1. |
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