Experimental and theoretical study of the complexation of the thallium cation with a hexaarylbenzene-based receptor |
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| Authors: | Emanuel Makrlík Petr Toman Petr Vaňura Rajendra Rathore |
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| Affiliation: | (1) Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic;(2) Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic;(3) Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Czech Republic;(4) Department of Chemistry, Marquette University, Milwaukee, WI, USA |
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| Abstract: | Abstract From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, the stability constant of a hexaarylbenzene-based receptor. Tl+ complex species dissolved in nitrobenzene saturated with water was determined. By using the quantum-mechanical density functional level of theory calculations, the most probable structure of this complex was derived. |
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