Doppler-free two-photon spectroscopy of the 2ν3 band of SF6 |
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Authors: | CW Patterson F Herlemont M Azizi J Lemaire |
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Institution: | Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 USA;Laboratoire de Spectroscopie Hertzienne, Université de Lille 1, F-59655 Villeneuve D''Ascq Cedex, France |
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Abstract: | The assignments of most of the observed Doppler-free two-photon spectra of the 2ν3 band of SF6 near the P(14)–P(20) lines of a 10-μm CO2 waveguide laser are reported. The rovibrational and anharmonic constants for this band were obtained, along with ground state constants determined from observed “forbidden” transitions. |
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