| 原子簇化合物的键价分析 |
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| 引用本文： | 李颖,张星晨.原子簇化合物的键价分析[J].高等学校化学学报,1993,14(4):523-526. |
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| 作者姓名： | 李颖 张星晨 |
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| 作者单位： | 辽宁大学化学系，石家庄师范专科学校化学系，石家庄师范专科学校化学系 沈阳 110036，石家庄，石家庄 |
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| 摘 要： | 根据原子簇化合物骨架的价电子结构及与配位体成键的性质,在确定原子簇骨架中存在的空轨道或孤对电子轨道数目后,按骨架价电子数目在骨架价成键轨道中的具体分配,推导了原子簇骨架的总键价数。再结合分子的几何构型,可以估计骨架中相邻原子间的成键情况。
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| 关 键 词： | 原子簇化合物 电子结构 键价 |
Analysis for Bond Valence in Cluster Compound |
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| LI Ying.Analysis for Bond Valence in Cluster Compound[J].Chemical Research In Chinese Universities,1993,14(4):523-526. |
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| Authors: | LI Ying |
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| Abstract: | Based on the electronic structure and chemical bonding properties of the skeleton-ligand bonds of the skeleton of a cluster compound, having determined the number of empty valence orbitals or lone pair electronic orbitals of the cluster, the number of total bond valence of the skeleton is obtained according to the distribution of the number of valence electrons of the skeleton in valence bonding orbitals of the skeleton, then the chemical bonding properties between neighbouring two atoms in the skeleton can be guessed with the configuration of the skeleton of the cluster compound. |
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| Keywords: | Cluster compound Electron configuration Bond valence |
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