Dimethyl dichloromalonate as a new synthetic equivalent of methyl dichloroacetate in the Darzens condensation期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Dimethyl dichloromalonate as a new synthetic equivalent of methyl dichloroacetate in the Darzens condensation

Authors:	E. A. Berdnikov V. A. Mamedov

Affiliation:	(1) V. I. Ul'yanov-Lenin Kazan'State University, 18 ul. Lenina, 420008 Kazan', Russian Federation;(2) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan', Russian Federation

Abstract:	Dimethyl dichloromalonate reacts with aldehydes in the presence of sodium methoxide to form-chloropyruvates,-chloroglycidates, or,-dichlorohydrins, depending on the nature of the aldehyde.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1544–1545, August, 1995.

Keywords:	dimethyl dichloromalonate Darzens reaction /content/p182502p1031k241/xxlarge945.gif" alt=" agr" align=" BASELINE" BORDER=" 0" >-chloroketones -chloroepoxides /content/p182502p1031k241/xxlarge945.gif" alt=" agr" align=" BASELINE" BORDER=" 0" >, /content/p182502p1031k241/xxlarge945.gif" alt=" agr" align=" BASELINE" BORDER=" 0" >-dichlorohydrins
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