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Fluorinated triazinones from hexafluoroacetone ethoxycarbonylimine
Authors:Sokolov  V. B.  Aksinenko  A. Yu.
Affiliation:(1) Institute of Physiologically Active Substances, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation
Abstract:The behavior of hexafluoroacetone ethoxycarbonylimine in cyclocondensation with different binucleophiles of the amidine type, viz., amino derivatives of N- and N,S-heterocycles, was studied. A preparative method for the synthesis of previously unknown annelated 2,2-bis(trifluoromethyl)-1,3,5-triazinones was developed.
Keywords:ethoxycarbonylimine of hexafluoroacetone  2-aminopyridines  2-aminothiazolines  2-aminothiazoles  2-aminothiadiazoles  2-aminobenzothiazoles  substituted annelated 2,2-bis(trifluoromethyl)-1,3,5-triazin-4(3H)-ones  cyclocondensation
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