Fluorinated triazinones from hexafluoroacetone ethoxycarbonylimine |
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Authors: | Sokolov V. B. Aksinenko A. Yu. |
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Affiliation: | (1) Institute of Physiologically Active Substances, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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Abstract: | The behavior of hexafluoroacetone ethoxycarbonylimine in cyclocondensation with different binucleophiles of the amidine type, viz., amino derivatives of N- and N,S-heterocycles, was studied. A preparative method for the synthesis of previously unknown annelated 2,2-bis(trifluoromethyl)-1,3,5-triazinones was developed. |
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Keywords: | ethoxycarbonylimine of hexafluoroacetone 2-aminopyridines 2-aminothiazolines 2-aminothiazoles 2-aminothiadiazoles 2-aminobenzothiazoles substituted annelated 2,2-bis(trifluoromethyl)-1,3,5-triazin-4(3H)-ones cyclocondensation |
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