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The influence of water on the physicochemical characteristics of 1-butyl-3-methylimidazolium bromide ionic liquid
Authors:L. M. Ramenskaya  E. P. Grishina  A. M. Pimenova  M. S. Gruzdev
Affiliation:(1) Institute of the Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia
Abstract:A modified synthesis of 1-butyl-3-methylimidazolium bromide (BMImBr) was suggested and performed, and some physicochemical properties of the product containing 0.64–13.6 wt % water were determined. Water increased the electrical conductivity and decreased the viscosity and melting point of the substance but weakly influenced its density. Water in amounts of 5–8 wt % (45–50 mol %) caused structural changes. The BMImBr · 0.5H2O crystal hydrate was found to be stable thermodynamically.
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