Phosphine-free rhodium-catalyzed hydroarylation of diaryl acetylenes with boronic acids |
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Authors: | Weiwei Zhang |
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Institution: | College of Chemistry and Materials Science, Wenzhou University, Wenzhou 325027, PR China |
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Abstract: | Rh(CO)2(acac) was found to be an efficient and simple catalyst in hydroarylation of diaryl acetylenes with boronic acids in the absence of phosphine ligand. Thus, triaryl-substituted olefins were prepared in good to excellent yields. No 1,4-rhodium shift was observed in the catalytic cycle. |
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