| Synthesis and Crystal Structure of Compound [Fe(Phen)_3][(μ-oxo)Fe_2Cl_6]DMF |
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| 作者姓名： | 陈之荣 李健晖 梁玉仓 |
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| 作者单位： | CHEN Zhi-Rong②a LI Jian-Huib LIANG Yu-Cangc a(Department of Chemistry,Fuzhou University,Fuzhou,Fujian 350002,China) b(College of Life Science,Fujian Agriculture Forestry University,Fuzhou,Fujian 350002,China) c(State Key Laboratory of Structural Ch |
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| 基金项目： | Supported by the foundation of Education Committee of Fujian Province (JB01045) |
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| 摘 要： | 1 INTRODUCTION Recently polynuclear iron (Ⅲ) clusters have attracted considerable attention in bioinorganic chemistry due to their presence in the protein ferritin and the related materical hemosiderin[1, 2]. The binuclear oxo-bridge non-haem iron com- plexes (containing the FeⅢOFeⅢ unit) which provide models for the diiron site in the protein involved in the storage (haemrythrin) and on the reductive activation (methanemonoxygenas, ribonclectidereductas) of dioxygen[3,4]. Also, wel…
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| 关 键 词： | molecular structure FeOFe (μ-oxo) diiron (Ⅲ) complexes synthesis |
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