Syntheses and thermal reactions of 2-alkyl(or aryl)-1-benzoyl-3,4-dihydro-2-thianaphthalenes |
| |
Authors: | Mikio Hori Tadashi Kataoka Hiroshi Shimizu Akihiko Tomoto |
| |
Institution: | Gifu College of Pharmacy, 6-1, Mitahora-higashi 5-chome, Gifu 502, Japan |
| |
Abstract: | 1-Benzoyl-2-methy1-3,4-dihydro-2-thianaphthalene () underwent novel intermolecular 1,4-rearrangement in refluxing toluene to give an enol ether , while rearrangement of 2-phenyl derivative proceeded intramolecularly in refluxing xylene to afford a 1,4-rearranged enol ether . On the other hand, ylides were refluxed in alcohols to afford some ring-opened products . |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|