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Regiochemistry of reactions of α-alkoxyallylphosphine oxide ylides with electrophiles.
Authors:Mehran Maleki  JAlien Miller  OWilliam Lever
Institution:Chemistry Department, The University, Dundee DD1 4HN, Scotland, U.K.;Department of Organic Chemistry, Wellcome Research laboratories Burroughs Wellcome Co., Research Triangle Park, N.C. 27709, U.S.A.
Abstract:Anions 4, derived from α-methoxyallylphosphine oxides 3, react with electrophiles in a highly regioselective fashion to give products of α-attack or γ-attack depending upon the substitution pattern of the ylid 4 and the nature of the electrophile.
Keywords:
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