Intramolecular silyl migration in the singlet oxygenation of 2-methyl-5-trimethylsilylfuran |
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Authors: | Waldemar Adam Augusto Rodriguez |
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Institution: | Departamento de Quimica, Universidad de Puerto Rico, Rio Piedras, Puerto Rico 00931, USA;Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-8700 Würzburg, BRD |
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Abstract: | Tetraphenylporphyrin-sensitized photooxygenation of 2-methyl-5-trimethylsilylfuran () affords quantitatively trimethylsilyl 2-oxo-4-pentenoate (), presumably via intramolecular Baeyer-Villiger rearrangement of the intermediary dioxirane (). |
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