Study of 7-azaindole in its first four singlet states |
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Authors: | Catalán J de Paz J L G |
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Institution: | Departamento de Química Física Aplicada, Universidad Autónoma, Cantoblanco, Madrid, Spain. javier.catalan@uam.es |
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Abstract: | The molecular structure and properties of 7-azaindole in its first four singlet states were studied with a view to improving current understanding of the photophysical behavior of its C(2h) dimer. This dimer, which exhibits a double proton transfer via its two hydrogen bonds upon electronic excitation, has for 35 years been used as a model for the photophysical behavior of DNA base pairs. Electronic excitation of 7-azaindole simultaneously increases its acidity and basicity; these changes facilitate a concerted mechanism for the double proton transfer in the dimer. In this work, we found the acidity and basicity changes to occur only in its first pi,pi(*) excited singlet state. |
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