| La2Zr2O7:Eu3+纳米棒的合成、表征及其荧光性能 |
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| 引用本文： | 宋荷娟,周立群,黄莹,李玲,王婷,杨兰.La2Zr2O7:Eu3+纳米棒的合成、表征及其荧光性能[J].化学物理学报,2013,26(1):83-87. |
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| 作者姓名： | 宋荷娟 周立群 黄莹 李玲 王婷 杨兰 |
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| 作者单位： | 湖北大学有机功能分子合成与应用教育部重点实验室，湖北大学化学化工学院，武汉 430062;湖北大学有机功能分子合成与应用教育部重点实验室，湖北大学化学化工学院，武汉 430062;湖北大学有机功能分子合成与应用教育部重点实验室，湖北大学化学化工学院，武汉 430062;湖北大学有机功能分子合成与应用教育部重点实验室，湖北大学化学化工学院，武汉 430062;湖北大学有机功能分子合成与应用教育部重点实验室，湖北大学化学化工学院，武汉 430062;湖北大学有机功能分子合成与应用教育部重点实验室，湖北大学化学化工学院，武汉 430062 |
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| 摘 要： | 采用传统固相法和水热法成功地制备出棒状La2Zr2O7:Eu3+荧光粉. 利用X射线粉末衍射仪、透射电镜和荧光光谱仪等分析了产物的结构、形貌和发光特性. 结果表明红色荧光粉La2Zr2O7:Eu3+有良好的晶相，属于立方结构，空间点群为Fd3m； 其形貌主要为纳米棒， 平均直径约47 nm， 长度为50～700 nm. 并对纳米棒的生长机理进行了探讨. 在466 nm蓝光激发下，La2Zr2O7:Eu3+荧光粉能发射出Eu3+的特征红色荧光，发射主峰位于616 nm处，归属于Eu3+的5DO→7F2超灵敏电偶极跃迁.此外，在产物的发射光谱中能够观察到5D1→7FJ (J=0, 1, 2)跃迁和5D1→7FJ (J=1, 2, 4)跃迁的劈裂峰，这说明Eu3+处在低对称性的晶体场格位中.
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| 关 键 词： | La2Zr2O7:Eu3+，烧绿石结构，纳米棒荧光性能 |
| 收稿时间： | 2012/11/18 0:00:00 |
Synthesis, Characterization and Luminescent Properties of La2Zr2O7:Eu3+ Nanorods |
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| He-juan Song,Li-qun Zhou,Ying Huang,Ling Li,Ting Wang and Lan Yang.Synthesis, Characterization and Luminescent Properties of La2Zr2O7:Eu3+ Nanorods[J].Chinese Journal of Chemical Physics,2013,26(1):83-87. |
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| Authors: | He-juan Song Li-qun Zhou Ying Huang Ling Li Ting Wang and Lan Yang |
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| Institution: | Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China;Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China;Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China;Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China;Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China;Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China |
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| Abstract: | |
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| Keywords: | La2Zr2O7:Eu3+ Pyrochlore structure Nanorod Luminescence |
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