Stability of s-, p-, and d-element diphosphates in water |
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| Authors: | G. S. Kuanysheva K. U. Dzhamansarieva G. Zh. Sdikova |
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| Affiliation: | (1) Al-Farabi State University of Kazakhstan, pr. al-Farabi 71, Almaty, 050038, Kazakhstan;(2) Satpaev State Technical University of Kazakhstan, ul. Satpaeva 23, Almaty, 050013, Kazakhstan |
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| Abstract: | The mean atomic Gibbs energies of formation of (Δ f ? at 0 ) of s-, p-, and d-element diphosphates have been calculated using ion increments of the Gibbs energy (Δ f G 0). The diphosphate hydrolysis kinetics is considered, and a correlation between the Δ f ? at 0 values and the hydrolysis rate constants is presented. |
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