Composition and reactivity of aminolysis products of phenyl glycidyl ether with benzylamine |
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| Authors: | V. A. Pal’chikov S. Yu. Mykolenko A. N. Pugach F. I. Zubkov |
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| Affiliation: | 1.Oles’ Honchar Dnepropetrovsk National University,Dnepropetrovsk,Ukraine;2.Dnepropetrovsk State Agrarian and Economic University,Dnepropetrovsk,Ukraine;3.RUDN University,Moscow,Russia |
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| Abstract: | Composition of aminolysis products of phenyl glycidyl ether with benzylamine in various conditions was studied. The ratio of 1-(benzylamino)-3-phenoxypropan-2-ol and 1,1'-(benzylazanediyl)bis(3-phenoxypropan-2-ol) does not considerably depend on the nature of the solvent and is basically determined by ratio of initial reagents. 2,6-Bis(phenoxymethyl)morpholine was obtained by dehydration of aminodiol in conditions of Mitsunobu reaction with subsequent reductive debenzylation. |
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