The Transition Products in Substitutional Photochemistry of [Mo(CN)8]4− – Theoretical Approach. X-ray Crystal Structure of (AsPh4)[W(bpy)(CN)6] |
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| Authors: | Tomasz Stawski Janusz Szklarzewicz Krzysztof Lewiński |
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| Institution: | (1) Faculty of Chemistry, Jagiellonian University, R. Ingradena 3, 30-060 Kraków, Poland |
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| Abstract: | The single crystal X-ray structure of (AsPh4)W(bpy)(CN)6] is described. The structure of octa- and hepta-coordinated intermediates of substitutional photolysis of Mo(CN)8]4− ion in aqueous media were determined by performing semi-empirical calculations. On the basis of obtained results as well
as on empirical data the photolysis scheme has been postulated. |
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