X-ray photoelectron and X-ray emission study of the electronic structure of hexanuclear Mn(II,III) pivalate complexes |
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| Authors: | A.?D.?Fedorenko mailto:fedorenko@niic.nsc.ru" title=" fedorenko@niic.nsc.ru" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,L.?N.?Mazalov,E.?Yu.?Fursova,V.?I.?Ovcharenko,A.?V.?Kalinkin,S.?A.?Lavrukhina |
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| Affiliation: | 1.Nikolaev Institute of Inorganic Chemistry, Siberian Branch,Russian Academy of Sciences,Novosibirsk,Russia;2.Novosibirsk National Research State University,Novosibirsk,Russia;3.International Tomography Center, Siberian Branch,Novosibirsk,Russia;4.Boreskov Institute of Catalysis, Siberian Branch,Novosibirsk,Russia |
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| Abstract: | ![]()
The electronic structure of hexanuclear Mn(II,III) pivalate complexes with tetrahydrofuran and isonicotinamide are studied by X-ray photoelectron spectroscopy and X-ray emission spectroscopy. It is shown that when isonicotinamide substitutes for tetrahydrofuran the spin state of manganese ions is retained; the electron density increases on the manganese and oxygen atoms of the [Mn6(O)2Piv10] core. |
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