Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides |
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| Authors: | Caron Laurence Campeau Louis-Charles Fagnou Keith |
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| Affiliation: | Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Canada K1N 6N5. |
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| Abstract: | Direct arylation reactions of nitrobenzenes and aryl halides occur in good yield and high ortho regioselectivity. These reactions can be performed on gram scale with as few as 3 equiv of the nitro arene relative to the aryl halide. The synthetic utility of this method is demonstrated via rapid synthesis of a Boscalid intermediate. |
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