Calorimetric determination of enthalpies,gibbs energies,and entropies of inclusion of some alcohols into α- and β-cyclodextrins in aqueous solutions |
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Authors: | Sadao Takagi Mune Maeda |
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Institution: | (1) Department of Chemistry, Faculty of Science and Technology, Kinki University, 3-4-1 Kowakae, 577 Higashi-osaka, Osaka, Japan |
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Abstract: | The enthalpies of transfer of cyclohexanol from aqueous to aqueous - or -cyclodextrin solutions have been measured at various mole fractions at 298.15 K on a rocking twin-microcalorimeter of heat-conduction type and the molar enthalpies, Gibbs energies, and entropies of inclusion in the aqueous solutions have been determined by the method proposed by the authors Netsu Sokutei
10, 103 (1983)], to elucidate the driving force of the molecular inclusion. Discussions are given for all the systems obtained by the authors, concluding that the driving force is the enhancement of the entropy.Calorimetric studies on molecular inclusion V. |
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