| 某些氨基取代环戊二烯配合物催化1,5-己二烯的高选择性环化 |
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| 引用本文： | 钱延龙,沙立克,黄吉玲,李政伟. 某些氨基取代环戊二烯配合物催化1,5-己二烯的高选择性环化[J]. 催化学报, 2000, 21(1): 1-2 |
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| 作者姓名： | 钱延龙 沙立克 黄吉玲 李政伟 |
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| 作者单位： | East China University of Science and Technology |
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| 基金项目： | 国家自然科学基金;29734145; |
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| 摘 要： | ![]()
We have interested for some years in studying organic reactions catalyzed by (RCp)2TiCl2/i-C3H7MgX, specially isomerization of non-conjugated dienes[1,2]. Titanocene complexes are also effective for some cyclization reactions[3]. In the case of isomerization of 1,5-hexadiene (HD), such catalysts usually result in a mixture of 1,4-hexadiene, 1,3-hexadiene, 2,4-hexadiene, methylenecyclopentane and methylcyclopentene. Our previous results showed that the product distribution largely depends on the characteristics of the substituents on cyclopentadienyl (Cp) ring[2].
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| 关 键 词： | 均相催化 环戊二烯基钛配合物 己二烯异构化 环化反应 反应机理 |
| 收稿时间： | 2000-02-25 |
Highly Selective Cyclization of 1,5-Hexadiene Catalyzed by Some Amino-Substituted Titanocene Complexes |
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| QIAN Yanlong,Mohammed Abu SALEQUE,HUANG Jiling,LI Zhengwei. Highly Selective Cyclization of 1,5-Hexadiene Catalyzed by Some Amino-Substituted Titanocene Complexes[J]. Chinese Journal of Catalysis, 2000, 21(1): 1-2 |
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| Authors: | QIAN Yanlong Mohammed Abu SALEQUE HUANG Jiling LI Zhengwei |
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| Abstract: | ![]()
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| Keywords: | cyclization hexadiene amino-substituted titanocene complex |
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