Recent advances in assemblies of cyclodextrins and amphiphiles: construction and regulation |
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| Affiliation: | 1. Department of Bioscience and Biotechnology, Bio/Molecular Informatics Center & Institute of Ubiquitous Information Technology and Applications (CBRU), Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 143-701, South Korea;2. Departments of Bacteriology and Genetics, University of Wisconsin, Madison, Wisconsin 53706, USA;3. Department of Biological Science & Center for Biotechnology Research in UBITA, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 143-701, South Korea;1. Department of Industrial Pharmacy, Daiichi University of Pharmacy, 22-1 Tamagawa-cho, Minami-ku Fukuoka, 815-8511, Japan;2. Department of Biophysical Chemistry, Faculty of Pharmaceutical Sciences, Nagasaki International University, 2825-7 Huis Ten Bosch, Sasebo, Nagasaki, 859-3298, Japan;1. School of Food and Chemical Engineering, Beijing Technology and Business University, Beijing 100048, PR China;2. China Rural Technology Development Center, Beijing 100045, PR China;1. Department of Chemistry, Sripat Singh College, Jiaganj, Murshidabad, WB 742123, India;2. Department of Chemistry, University of North Bengal, Darjeeling 734013, India;3. Department of Chemistry, Government General Degree College, Pedong, Kalimpong 734311, India;4. Department of Chemistry, Parimal Mitra Smriti Mahavidyalaya, Malbazar, Jalpaiguri, WB 735221, India;5. Department of Chemistry, Alipurduar University, Alipurduar, WB 736122, India;1. Laboratorio de Biofisicoquímica, Departamento de Fisicoquímica, Facultad de Química, Universidad Nacional Autónoma de México, CdMx 04510, Mexico;2. Department of Physical Chemistry, University of Chemistry and Technology, Technická 5, 166 28 Prague 6, Czech Republic |
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| Abstract: | 
Cyclodextrins (CDs) had been regarded as destructors in molecular assembly systems for a long time until CD/surfactants were found to assemble into high order structure driven by hydrogen bonding between CDs. Thereafter, intensive researches have been conducted on construction and regulation of CD–amphiphile systems. Here, we summarized the recent progress on construction and regulation of CDs and amphiphiles assembly. The scope of amphiphiles have been extended from surfactants (ionic surfactants, zwitterion surfactants, nonionic surfactants, gemini surfactant, and so on), to nontypical amphiphiles (amines, aromatic molecules, alkanes, and so on). Owing to the abundant choices of guest amphiphiles and dynamic nature of host–guest inclusive interaction, numerous regulation methods (such as enzyme, light, pH, concentration, temperature, and so on) have been used in CD–amphiphile systems. Moreover, remarks and future perspectives are also discussed at the end of this review, which is expected to stimulate progress on both mechanism and application level. |
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| Keywords: | Cyclodextrins Amphiphiles Non-typical amphiphiles Regulation Light Enzyme |
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