Thermal Decomposition of Fullerene Derivatives A Synthesis Method of New Fullerene Based Molecules |
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| Authors: | Dragoe N. Nakahara K. Xiao L. Shimotani H. Kitazawa K. |
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| Affiliation: | (1) Department of Applied Chemistry, Hongo, University of Tokyo, 7-3-1, Bunkyo-ku, Tokyo, Japan;(2) Faculty of Chemistry, Department of Physical Chemistry, University of Bucharest, Blvd. Elisabeta, 4-12 Bucharest, Romania |
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| Abstract: | The thermal decomposition of methano-fullerene derivatives such as ethoxycarbonyl methano[60] fullerene and various isomers of bis-(ethoxycarbonyl methano)[60] fullerene leads to new fullerene derivatives, which have been preliminary characterized. The analysis of separated species was performed by UV-VIS, IR, H- and C-NMR, STM, FAB, LDI and MALDI-TOF MS spectroscopy. One of the isolated phases is a C122 molecule with a dumbbell-like structure. This revised version was published online in July 2006 with corrections to the Cover Date. |
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| Keywords: | fullerene dimers [60]fullerene thermal decomposition |
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