| Hydrothermal Synthesis and Crystal Structure of a Nickel（Ⅱ） Polymer with a One-dimensional Chain Structure：[Ni（cbba）_2（bipy）（H_2O）_2]_n |
| |
| 引用本文： | 李秀梅,王庆伟,王志涛,刘博.Hydrothermal Synthesis and Crystal Structure of a Nickel（Ⅱ） Polymer with a One-dimensional Chain Structure：[Ni（cbba）_2（bipy）（H_2O）_2]_n[J].结构化学,2011,30(2):176-179. |
| |
| 作者姓名： | 李秀梅 王庆伟 王志涛 刘博 |
| |
| 作者单位： | Department;Chemistry;Tonghua;Teachers;College;Jilin;Normal;University; |
| |
| 基金项目： | the Science and Technology Research Projects of the Education Department of Jilin Province (No. 2009. 272) |
| |
| 摘 要： | A metal-organic coordination polymer formulated as Ni(cbba) 2 (bipy)(H 2 O) 2 ] n 1 (H 2 cbba=2-(4-chlorine-benzoyl)benzoic acid,bipy=4,4-bipyridine) has been hydrothermally synthesized and structurally characterized by elemental analysis,IR spectrum,TG and single-crystal X-ray diffraction.The title compound crystallizes in the triclinic system,space group P1 with a=5.4550(4),b=11.4099(8),c=15.3135(11),α=68.7680(10),β=81.3470(10),γ=79.3450(10)o,V=869.48(11) 3,C 38 H 28 Cl 2 N 2 NiO 8,M r=770.23,D c=1.471 g/cm 3,μ(MoKα)=0.768 mm 1,F(000)=396,Z=1,the final R=0.0456 and wR=0.1171 for 2477 observed reflections (I > 2σ(Ⅰ)).It exhibits a one-dimensional chain-like structure.
|
| 关 键 词： | 一维链状结构 配位聚合物 晶体结构 水热合成 联吡啶 氧化镍 链结构 标题化合物 |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
