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Fourier transform infrared spectroscopy as a tool for the study of rare earths carbohydrates complexes
Authors:Hong Liang  Hai Guo  Duan -Fu Xu  Jin -Guang Wu
Affiliation:(1) Department of Chemistry, Peking University, Beijing, People's Republic of China;(2) Institute of Chemistry, Academia Sinica, Beijing, People's Republic of China
Abstract:
FT-IR spectra of the mixtures of praseodymium chloride and glucose in glassy state were investigated. From the changes of relative intensity and shifts of the characteristic frequency of glucose and water, it is concluded that the coordinated water molecules of the praseodymium ions are partially substituted by glucose through O-H groups which coordinated with praseodymium ions to form chelate ions.
Keywords:FT-IR spectra  praseodymium-glucose complex  glassy glucose
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