Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal-organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction |
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| Authors: | Dietzel Pascal D C Johnsen Rune E Fjellvåg Helmer Bordiga Silvia Groppo Elena Chavan Sachin Blom Richard |
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| Affiliation: | SINTEF Materials & Chemistry, P.O. Box 124 Blindern, N-0314, Oslo, Norway. |
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| Abstract: | The microporous metal-organic framework Ni(2)(dhtp) (H(4)dhtp=2,5-dihydroxyterephthalic acid) shows distinct end-on CO(2) coordination to coordinatively unsaturated nickel sites giving rise to high CO(2) adsorption capacity at sub-atmospheric pressures and ambient temperatures. |
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