| Design and Synthesis of Novel Molecular Tweezers Derived from Chenodeoxycholic Acid |
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| 引用本文： | ZhiGangZHAO QiMingMU ShuHuaCHEN. Design and Synthesis of Novel Molecular Tweezers Derived from Chenodeoxycholic Acid[J]. 中国化学快报, 2004, 15(11): 1285-1288 |
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| 作者姓名： | ZhiGangZHAO QiMingMU ShuHuaCHEN |
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| 作者单位： | TheFacultyofChemistry,SichuanUniversity,Chengdu610064 |
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| 摘 要： | A novel type of chiral molecular tweezers has been designed and synthesized by usingchenodeoxy cholic acid as spacer and the aromatic compounds as arm. Their structures werecharacterized by 1HNMR, IR, MS spectra and elemental analysis. These chiral molecular tweezersshowed good enantioselectivity for D-amino acid methyl esters.
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| 关 键 词： | 设计 合成 分子镊子 分子识别 鹅胆酸 结构表征 D-氨基酸甲基酯 |
Design and Synthesis of Novel Molecular Tweezers Derived from Chenodeoxycholic Acid |
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| Zhi Gang ZHAO,Qi Ming MU,Shu Hua CHEN The Faculty of Chemistry,Sichuan University,Chengdu. Design and Synthesis of Novel Molecular Tweezers Derived from Chenodeoxycholic Acid[J]. Chinese Chemical Letters, 2004, 15(11): 1285-1288 |
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| Authors: | Zhi Gang ZHAO Qi Ming MU Shu Hua CHEN The Faculty of Chemistry Sichuan University Chengdu |
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| Affiliation: | Zhi Gang ZHAO,Qi Ming MU,Shu Hua CHEN* The Faculty of Chemistry,Sichuan University,Chengdu 610064 |
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| Abstract: | A novel type of chiral molecular tweezers has been designed and synthesized by using chenodeoxy cholic acid as spacer and the aromatic compounds as arm. Their structures were characterized by 1HNMR, IR, MS spectra and elemental analysis. These chiral molecular tweezers showed good enantioselectivity for D-amino acid methyl esters. |
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| Keywords: | Molecular tweezers synthesis chenodeoxycholic acid recognition. |
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