Photocatalytic hydrogen production from water in self-assembled supramolecular iridium-cobalt systems |
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| Authors: | Jasimuddin Sk Yamada Tomoko Fukuju Kazunori Otsuki Joe Sakai Ken |
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| Institution: | The Center for Creative Materials Research, Research Institute of Science and Technology, College of Science and Technology, Nihon University, 1-8-14 Kanda Surugadai, Chiyoda-ku, Tokyo 101-8308, Japan. |
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| Abstract: | Supramolecular photosynthetic systems made up of the Ir(ppy)(2)(bpy)](+) and Co(bpy)(3)](2+) cores (ppy = 2-phenylpyridinate, bpy = 2,2'-bipyridine) are in situ self-assembled in aqueous media to generate H(2) upon visible light irradiation, where one of them recorded a relatively high turnover number of 20. |
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