Synthese und Kernresonanzspektren von Methylphenyl-substituierten Trisilylphosphanen PSi3
Me
n
Ph
9−n |
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Authors: | Karl Hassler |
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Institution: | (1) Institut für Anorganische Chemie, Technische Universität Graz, A-8010 Graz, Österreich |
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Abstract: | Trisilylphosphanes of the type PSi3
Me
x
Ph
9–x
are formed when sodium/potassiumphosphide reacts with methylphenylchlorosilanesMe
n
Ph
3–n
SiCl or with mixtures of methylphenylchlorosilanes. The phosphanes (SiMe
3)
n
P (SiMe
m
Ph
3–m
)3–n
(n, m=0, 1, 2, 3) were separated and purified by destillation or crystallization and their29Si as well as31P-NMR-spectra were recorded. |
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Keywords: | Methylphenyltrisilylphosphanes 31P-NMR-Spectra 29Si-NMR-Spectra |
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