Highly efficient and convenient asymmetric hydrosilylation of ketones catalyzed with zinc Schiff base complexes |
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| Authors: | Shuai Liu Jiajian Peng Hu Yang Ying Bai Jiayun Li Guoqiao Lai |
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| Institution: | Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, 222 Wenyi Rd, Hangzhou 310012, China |
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| Abstract: | Several chiral Schiff base ligands derived from α-amino acids were prepared, and zinc complexes with these chiral Schiff base ligands prepared were tested for the catalytic asymmetric hydrosilylation of ketones, and the results showed that excellent ee values were obtained, which are the prominent examples of catalytic asymmetric hydrosilylation of ketones catalyzed with zinc complexes in the presence of readily available and inexpensive α-amino acids based Schiff base ligands. |
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