Monolayered adatom aggregation induced by metallofullerene molecules on Cu(100) |
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Authors: | Jun Zhang Shixiong Zhao Bingkai Yuan Ke Deng Baoyun Sun Xiaohui Qiu |
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Institution: | 1. National Center for Nanoscience and Technology, Zhongguancun Beiyitiao No. 11, Beijing, China;2. Academy for Advanced Interdisciplinary Studies, Peking University, Haidian District, Yiheyuan Road 5, Beijing, China;3. CAS Key Lab for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Shijingshan District, Yuquanlu 19B, Beijing, China |
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Abstract: | The adsorption and self-assembly of Gd@C82 molecules on Cu(100) surface have been investigated using scanning tunneling microscopy (STM). The metallofullerene molecules in the assemblies showed two characteristic apparent heights in the STM images. STM manipulation and spectroscopy was performed and revealed the formation of Cu adatom islands underneath the Gd@C82 molecules. The monolayered Cu aggregates were resulted from the adatom–molecule complexation, which is supported by density functional theory (DFT) calculations that show charge transfer and electrostatic interactions between Gd@C82 and adatoms. In addition, sub-molecularly resolved STM images demonstrated the structural and orientational ordering of Gd@C82 assemblies upon thermal annealing. DFT calculations demonstrated that Gd atom located at the lower part of the carbon cage is a favored adsorption configuration for Gd@C82 molecules adsorbed on Cu(100). |
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