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N,N′-双(4-甲基-2-苯并噻唑基)-2,6-吡啶二酰胺钴(Ⅱ)配合物的合成和晶体结构(英)
引用本文:刘生桂,刘玮,李一志,游效曾.N,N′-双(4-甲基-2-苯并噻唑基)-2,6-吡啶二酰胺钴(Ⅱ)配合物的合成和晶体结构(英)[J].无机化学学报,2005,21(4):543-545.
作者姓名:刘生桂  刘玮  李一志  游效曾
作者单位:南京大学配位化学研究所,配位化学国家重点实验室,南京 210093,南京大学配位化学研究所,配位化学国家重点实验室,南京 210093,南京大学配位化学研究所,配位化学国家重点实验室,南京 210093,南京大学配位化学研究所,配位化学国家重点实验室,南京 210093
基金项目:国家重大基础研究发展项目(No.G2000077500),国家自然科学基金(No.NSF90101028,20201006)资助项目。
摘    要:Treatment of deprotonated N,N′-bis(4-methyl-2-benzothiazolyl)-2, 6-pyridicarboxamide (L2-) with CoCl2·6H2O yields the mononuclear complex, (Et4N)2CoL2]·0.5H2O. Single crystal X-ray structural determination has been carried out for the complex, crystal system: Monoclinic, space group: P21/c, a=1.444(1) nm, b=1.969(1) nm, c=2.448(1) nm, β=118.02(1)°, V=6.143 0(15) nm3, Z=4. In this complex, the central Co(Ⅱ) atom is in an octahedron environment, with four deprotonated amide-N atoms in the equatorial plane and two pyridine-N atoms in the axial positions. CCDC: 252558.

关 键 词:2,6-吡啶酰胺    钴配合物    合成    晶体结构
收稿时间:2004/11/4 0:00:00
修稿时间:2004/12/16 0:00:00

The Synthesis and Crystal Structure of An N, N'-bis(4-methyl-2-benzothiazolyl)- 2, 6-pyridicarboxamide Co(
LIU Sheng-Gui,LIU Wei,Li Yi-Zhi and YOU Xiao-Zeng.The Synthesis and Crystal Structure of An N, N''''-bis(4-methyl-2-benzothiazolyl)- 2, 6-pyridicarboxamide Co([J].Chinese Journal of Inorganic Chemistry,2005,21(4):543-545.
Authors:LIU Sheng-Gui  LIU Wei  Li Yi-Zhi and YOU Xiao-Zeng
Institution:Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093
Abstract:
Keywords:2  6-pyridicarboxamide  cobalt complex  synthesis  crystal structure
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