Facile preparation of transparent monolithic titania gels utilizing a chelating ligand and mineral salts |
| |
Authors: | George Hasegawa Kazuyoshi Kanamori Kazuki Nakanishi Teiichi Hanada |
| |
Institution: | (1) Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo-ku, Kyoto 606-8502, Japan; |
| |
Abstract: | Highly homogeneous transparent titania gels have been successfully prepared from titanium alkoxide by a sol–gel method utilizing
chelating agent, ethyl acetylacetate (EtAcAc), in the presence of strong acid anions. Only catalytic amount of a strong acid
anion suppress the rapid hydrolysis of titanium alkoxide by blocking the nucleophilic attack of HO− and H2O, and the resultant moderate sol–gel reactions thus afford homogeneous gelation, leading to transparent monolithic titania
gels. Gelation time can be widely controlled by changing amounts of water, chelating agent and salt. The ability of salts
to suppress the too abrupt sol–gel reactions is strongly dependent on the electronegativity of anions and valence of cations.
With employing NH4NO3 as a suppressing electrolyte, the obtained titania gels can be converted to pure TiO2 by simple washing and heat-treatment, and transformations to anatase and rutile structures were found to start at 400 and
600 °C, respectively. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|