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New activated bisfluoroaromatic compounds
Authors:A L Rusanov  M L Keshtov  N M Belomoina  A K Mikitaev  G B Sarkisyan  S V Keshtova
Institution:(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation
Abstract:Bis (p-fluorophenylethynyl) derivatives were obtained by the reaction of bisbromoaromatic compounds withp-fluorophenylacetylene in the presence of a Pd catalyst. Subsequent oxidation of these products using an I2-DMSO system led to new bis(p-fluorophenylglyoxaly)ketones, α-diketones, and heterocyclic compounds. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 810–812, April, 1997.
Keywords:bisbromoaromatic compounds            p-fluorophenylacetylene  bisfluoroaromatic compounds  bis(p-fluorophenylethnyl) ketones  diazines  and imidazoles  cross-coupling reactions  bis(p-fluorophenylglyoxalyl) ketones  diazines  and imidazoles
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