Testing the photocatalytic activity of cyanogen-and thiocyanogen-based inorganic polymers |
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Authors: | Z. Tóth Zs. Zsótér M. T. Beck |
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Affiliation: | (1) Department of Physical Chemistry, Kossuth Lajos University, H-4010 Debrecen, Hungary |
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Abstract: | The photocatalytic properties of some cyanogen-and thiocyanogen-based inorganic polymers, such as paracyanogens containing different metals (Hg, Ag, Cu), polythiocyanogens of different iodine contents, polycyanogen and poly (cyanogenthiocyanate), have been tested in two systems. Cu-containing paracyanogen and the iodine-poor polythiocyanogens catalyze the photoreduction of methylviologen under visible light, furthermore the Cu-containing paracyanogen catalyzes the photoreduction of water to hydrogen under UV irradiation.
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