Synthesis and Cationic Polymerization of Open-Chain and Cyclic Enol Ethers |
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| Authors: | J V Crivello T Yoo |
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| Institution: | Department of Chemistry , Rensselaer Polytechnic Institute , Troy, New York, 12180, USA |
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| Abstract: | Abstract Several new open-chain and cyclic enol ether monomers were prepared using simple, straightforward procedures. The reactivities of these monomers were compared using both differential scanning photocalorimetry and Fourier transform real-time infrared spectroscopy. In general, these new monomers were found to possess excellent reactivity in photoinitiated cationic polymerization using a diaryliodonium salt photoinitiator. |
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| Keywords: | Photoinitiated cationic polymerization Enol ethers Cyclic enol ethers Polymerization reactivity |
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