Characterization of Nitro-Substituted Polybenzimidazole Synthesized by the Reaction with Nitric Acid |
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| Authors: | Jin Hyun Choi Won Seok Lyoo Wan Shik Ha Volker Rossbach |
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| Institution: | 1. Department of Fiber and Polymer Science College of Engineering , Seoul National University , San 56-1, Shinlim-Dong, Kwanak-Gu, Seoul, 151-742, Korea;2. Institut für Technische und Makromolekulare Chemie Universit?t Hamburg , Bundesstrasse 45, D20146, Hamburg, Germany;3. Institut für Makromolekulare Chemie und Textilchemie, Technische Universit?t Dresden , 01062, Dresden, Germany |
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| Abstract: | Abstract Nitro-substituted poly2,2′-(m-phenylene)-5,5′-bibenzimidazole]s (PBIs) were synthesized by the reaction of PBI with nitric acid in sulfuric acid under various conditions. The number of nitro groups substituted on the aromatic ring of PBI per polymeric unit varied from 1.44 to 3.55 according to the reaction conditions. An increase in reaction temperature and concentration of the nitric acid increased the degree of substitution. The inherent viscosity of the substituted polymer increased as the reaction temperature decreased. When the reaction temperature was 30°C, the inherent viscosity of the polymer increased as the concentration of nitric acid increased. The nitro-substituted PBI exhibited polyelectrolyte behavior in formic acid. The nitro groups substituted on PBI were dissociated when the polymer was heated to 450°C, displaying exothermic behavior, and the decomposition of polymer was proportional to its nitro group content. All nitro-substituted PBIs showed better solubilities in polar aprotic and acidic solvents, such as dimethylacetamide, dimethylsulfoxide, dimethylformamide, N-methylpyrrolidone, formic acid, sulfuric acid, and trifluoromethanesulfonic acid. |
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