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Structure and Molecular Recognition of Chiral Amino-Cyclodextrin: One-dimensional Array by Self-assembly in Solid and Chiral Discrimination in Solution |
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| Authors: | Noboru Yoshida Kazuaki Harata Tetsuya Inoue Naohito Ito Kazuhiko Ichikawa |
| Institution: | 1. Laboratory of Molecular Functional Chemistry, Division of Material Science , Graduate School of Environmental Earth Science, Hokkaido University , Sapporo, 060, Japan;2. National Institute of Bioscience and Human Technology , 1-1 Higashi, Tsukuba, Ibaraki, 305, Japan |
| Abstract: | Abstract The crystal structure and molecular recognition behaviour of a new chiral-amino cyclodextrin are reported; van der Waals interaction, hydrogen bond and the electrostatic interactions play an important role in the self-assembling process and chiral recognition for (R)-(-)-and (S)-(+)-mandelic acid. |
| Keywords: | Molecular recognition cyclodextrin self-assembly chirality x-ray structure |