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Control of hydrogen bonding in the design of new diol lattice inclusion compounds
Authors:Roger Bishop  Donald C. Craig  Ian G. Dance  Sungho Kim  Md. Aminul I. Mallick  Kim C. Pich
Affiliation:School of Chemistry, The University of New South Wales , Kensington, New South Wales, 2033, Australia
Abstract:
Abstract

In order to be able to predict and then synthesize new lattice inclusion compounds with the helical tubuland diol host structure, the hydrogen bonding modes of a range of bicyclic and tricyclic diols have been studied using X-ray crystallography. Several distinct types of lattice structure have been recognized. Steric factors play a major role in determining which of these is produced in a given case. Establishment of a series of structural rules provides a window of opportunity for duplication of the helical tubuland host lattice by deliberate design and synthesis. New inclusion compounds resulting from this approach are presented.
Keywords:
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