| 含氮聚合物负载钯络合物的合成及其催化加氢性能的研究 |
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| 引用本文： | 何炳林,孙君坦,王俐.含氮聚合物负载钯络合物的合成及其催化加氢性能的研究[J].高等学校化学学报,1988,9(9):945. |
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| 作者姓名： | 何炳林 孙君坦 王俐 |
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| 作者单位： | 南开大学高分子化学研究所 |
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| 摘 要： | 合成了一系列含氮聚合物金属络合物,考察了它们对1,5,9-环十二碳三烯选择性催化加氢的活性及选择性。研究了同种聚合物中单原子配体与双原子配体对催化剂活性的影响。对不同金属物种、孔结构、温度及压力对加氢活性及选择性的影响也进行了系统的比较。
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| 关 键 词： | 含氮聚合物负载钯络合物 催化加氢活性 选择性 |
| 收稿时间： | 1987-01-17 |
Synthesis of Several Polymer-Supported N-Pd Complex Catalysts and Their Catalytic Activity for the Hydrogenation of 1,5,9-Cyclododecatriene |
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| He Binglin,Sun Juntan,Wang Li.Synthesis of Several Polymer-Supported N-Pd Complex Catalysts and Their Catalytic Activity for the Hydrogenation of 1,5,9-Cyclododecatriene[J].Chemical Research In Chinese Universities,1988,9(9):945. |
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| Authors: | He Binglin Sun Juntan Wang Li |
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| Institution: | Institute of Polymer Chemistry, Nankai University, Tianjin |
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| Abstract: | Many polymer-supported palladium complex catalysts were prepared.The selective hydrogenation of 1,5,9-cyclododecatriene .with polymeric N-Pd complexes in 1:1 benzene-ethanol at 100℃ and 20 kg/cm2 was investigated. The relation-ships between the N-substituted groups and the active centre from the catalysts were examined.It was found that the catalysts containing chelating ligands displayed high activity for selective hydrogenation. |
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| Keywords: | Polymer-Supported N-Pd Complex Catalytic activity for the Hydrogenation Selection |
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