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Synthesis of bis(sigma-aryl)dirhodium(III) caprolactamates by oxidative arylation with arylboronic acids
Authors:Xie Jian-Hua  Nichols Jason M  Lubek Conrad  Doyle Michael P
Institution:Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA.
Abstract:Recently discovered stable bis(sigma-phenyl)dirhodium(III) caprolactamate and its substituted derivatives are conveniently prepared in high yields from dirhodium(II) caprolactamate and commercially available arylboronic acids in a copper-catalyzed process.
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