Thermochemistry of the complexes of some microelements and histidine |
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| Authors: | Chen S. Gao Sh Yang X. Hu R. Shi Q. |
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| Affiliation: | (1) Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi'an, 710069, P.R. China;(2) 330047 Nanchang Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University Institute of Modern Applied Chemistry, Xi'an, 710069, P.R. China |
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| Abstract: | ![]()
Solid complexes of M(His)2Cl2·nH2O (M=Mn, Co, Ni, Cu) of MnCl2·6H2O, CoCl2·6H2O, NiCl2·6H2O, CuCl2·2H2O and L-α-histidine (His) have been prepared in 95% ethanol solution and characterized by elemental analyses, chemical analyses, IR and TG-DTG. The constant-volume combustion energies of the complexes have been determined by a rotating-bomb calorimeter. And the standard enthalpies of formation of the complexes have been calculated as well. This revised version was published online in August 2006 with corrections to the Cover Date. |
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| Keywords: | histidine transition metal ion characterization standard enthalpy of formation solid complex |
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