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稀土材料红外多光子量子剪裁现象
引用本文:陈晓波,杨国建,张蕴芝,邓志威,胡丽丽,李崧,于春雷,陈志坚,崔建生,陈晓端,周宏余,吴正龙.稀土材料红外多光子量子剪裁现象[J].光谱学与光谱分析,2012,32(10):2597-2600.
作者姓名:陈晓波  杨国建  张蕴芝  邓志威  胡丽丽  李崧  于春雷  陈志坚  崔建生  陈晓端  周宏余  吴正龙
作者单位:1. 北京师范大学应用光学北京重点实验室, 北京 100875
2. 中国科学院物理研究所,北京 100190
3. 中国科学院上海光机所,上海 201800
4. 北京大学物理学院,北京 100871
5. 北京大学化学与分子工程学院,北京 100871
基金项目:国家自然科学基金项目(10674019);中央高校基本科研业务费专项项目资助
摘    要:稀土红外量子剪裁为目前国内外的研究热点,它对于提高太阳能电池的效率从而减低太阳能发电的造价很有意义。论文综述了稀土红外量子剪裁的研究意义,在总结了太阳能电池发电和损耗的原理的基础上,分析了稀土红外量子剪裁提高太阳能电池效率的具体途径。同时综述了单掺Er3+材料的稀土红外量子剪裁发光现象:光激发2H11/2能级有很强的4I13/2→4I15/2红外量子剪裁发光,速率很大的{2H11/2→4I9/2,4I15/2→4I13/2}交叉能量传递为导致光激发2H11/2能级有高量子剪裁效率的主要原因。

关 键 词:太阳能电池  稀土红外量子剪裁  
收稿时间:2012-03-27

Infrared Multiphoton Quantum Cutting Phenomena of Rare Earth Materials
CHEN Xiao-bo,YANG Guo-jian,ZHANG Yun-zhi,DENG Zhi-wei,HU Li-li,LI Song,YU Chun-lei,CHEN Zhi-jian,CUI Jian-sheng,CHEN Xiao-duan,ZHOU Hong-yu,WU Zheng-long.Infrared Multiphoton Quantum Cutting Phenomena of Rare Earth Materials[J].Spectroscopy and Spectral Analysis,2012,32(10):2597-2600.
Authors:CHEN Xiao-bo  YANG Guo-jian  ZHANG Yun-zhi  DENG Zhi-wei  HU Li-li  LI Song  YU Chun-lei  CHEN Zhi-jian  CUI Jian-sheng  CHEN Xiao-duan  ZHOU Hong-yu  WU Zheng-long
Institution:1. Applied Optics Beijing Area Major Laboratory, Beijing Normal University, Beijing 100875, China2. Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China3. Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China4. Physics School, Peking University, Beijing 100871, China5. Chemistry and Molecular Engineering School, Peking University, Beijing 100871, China
Abstract:Infrared quantum cutting of rare earth ion is an international hot research field. It is significant for the enhancement of solar cell efficiency and for the reduction of solar cell price. The present paper summarizes the research significance of infrared quantum cutting of rare earth ion. Based on the summarization of general principle and loss mechanism of solar cell, the possible method to enhance the solar cell efficiency by infrared quantum cutting is analyzed. Meanwhile, the present paper summarizes the infrared quantum cutting phenomena of Er3+ ion single-doped material. There is intense 4I13/2→4I15/2 infrared quantum cutting luminescence of Er3+ ion when the 2H11/2 energy level is excited. The intense {2H11/2→4I9/2,4I15/2→4I13/2} cross energy transfer is the main reason for the result in the high quantum cutting efficiency when the 2H11/2 energy level is excited.
Keywords:Solar cell  Infrared quantum cutting  Rare earth ion  
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