Optical absorption spectra of LiNbO3, Fe:LiNbO3, and Zn:Fe:LiNbO3 single crystals grown by Bridgman method |
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| Authors: | Haiping Xia Xianlin Zeng Jinhao Wang Jianli Zhang Jian Xu Yuepin Zhang Qiuhua Nie |
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| Abstract: | The optical absorption spectra of LiNbO3 (LN), Fe:LiNbO3 (Fe:LN), and Zn:Fe:LiNbO3 (Zn:Fe:LN) single crystals grown by Bridgman method were measured and compared. The absorption characteristics of the samples and the effects of growth process conditions on the absorption spectra were investigated. The Fe, Zn and Li concentrations in the crystals were analyzed by inductively coupled plasma (ICP) spectrometry. The results indicated that the overall Fe ion and Fe2+ concentration in Fe:LN and Zn:Fe:LN crystals increased along the growing direction. The incorporation of ZnO in Fe:LN crystal induced increase of Fe2+ in the crystal. Among Fe‐doped and Zn:Fe‐codoped LN single crystals, 3 mol% ZnO doped Fe:LN had a biggest change of Fe2+ ion concentration from bottom to top part of crystal. The effects of technical conditions (atmosphere and thermal history) on Fe2+ ion concentration were discussed. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) |
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| Keywords: | single crystal lithium niobate doped lithium niobate optical absorption spectra Bridgman method Fe2+ ion Zn2+ ion |
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