Addition of dipropylamine to multiacrylate and its model compound catalyzed by lithium dipropylamide |
| |
Authors: | Zbigniew Draczyski and Roman Jantas |
| |
Institution: | (1) Department of Physical Chemistry of Polymers, Technical University of Łódź, 90-924 Łódź, Poland |
| |
Abstract: | The nucleophilic addition reaction of dipropylamine to vinyl groups of multiacrylate - poly(2-acryloyloxyethyl methacrylate)
and to 2-butyrylethyl acrylate as model compound has been investigated. Based on the results obtained, it has been shown that
the addition reaction rate of dipropylamine to multiacrylate and 2-butyrylethyl acrylate is proportional to CH2=CH-] and to (C3H7)2NLi] with the ratio (C3H7)2NH]o/(C3H7)2NLi]o = 20. Second-order addition reaction rate constants and activation energies for the systems under investigation have been
determined.
This revised version was published online in August 2006 with corrections to the Cover Date. |
| |
Keywords: | poly(2-acryloyloxyethyl methacrylate) Addition reaction dipropylamine |
本文献已被 SpringerLink 等数据库收录! |